For A Proper Pretzel Crust, Count On Chemistry And Memories (2024)

Bavarian pretzels baked at the Goetz bakery in Taufkirchen, Germany, for the Oktoberfest beer festival. Miguel Villagran/Getty Images hide caption

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For A Proper Pretzel Crust, Count On Chemistry And Memories (2)

Bavarian pretzels baked at the Goetz bakery in Taufkirchen, Germany, for the Oktoberfest beer festival.

Miguel Villagran/Getty Images

As Oktoberfest starts in Munich every September, my mom starts making pretzels in Michigan. She says the soft pretzels in the U.S. aren't like what she was used to in Germany, and if she's going to be hosting a backyard Oktoberfest, her food should be authentic.

As a kid I watched the flour, yeast and salt whirl together in a food processor until suddenly congealing into a sticky ball. I liked to put my hand on the risen dough and pat it like a warm, soft belly. I helped dip the pretzels into something bubbling in the pot on the stove, careful not to touch the rolls after they were out of the bath.

That's because that bath was actually a caustic alkaline solution. Traditional Bavarian pretzels are dipped in a lye solution before they are baked. Lye, also known as sodium hydroxide, is essentially the same stuff that's used to make soap and clean drains. It can even dissolve glass.

But it's also what makes a good pretzel, says Wolfgang Büchler, owner of the Heidelberg Pastry Shoppe in Arlington, Va.. The shop is named after his German hometown.

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Büchler's employees snap on rubber gloves before dipping their handmade pretzels in the lye solution before baking. The solution, which Büchler imports from Germany, doesn't look like much; it's a dingy brown color. But it changes the pretzel's flavor and color in a way you can't really explain until you taste it, he says.

Lye can be toxic in high concentrations, but is also commonly used for curing foods like lutefisk. Most bakers use food-grade lye, which is the chemical equivalent of drain cleaner, but is produced and packaged in a clean, regulated way.

Since the lye dip is heavily diluted and the pretzel is baked after dipping, it won't kill you. Nonetheless, Della Limbert, a tour guide at Julius Sturgis Pretzel Bakery in Lititz, Pa., says the Julius Sturgis factory prefers a less risky mix of hot water and special baking soda flakes instead.

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Those flakes are more caustic than the baking soda you buy at the grocery store, but not nearly as caustic as lye. They essentially do the same job.

In case you were wondering, George Preti, a chemist at the Monell Chemical Senses Center, says baking soda maxes out at about 9.5 on the pH scale (which measures how acidic a substance is), while lye can get up to 14 (the highest ranking).

The dipping process is an important part of pretzel baking — it doesn't matter if it's a Philly-style pretzel (shaped like an elongated figure eight) or a hard pretzel you'd find at a gas station (baked twice as long).

"If you don't put a browning agent on the product, the pretzel is white," says Tony Tonelli, owner of Center City Soft Pretzel Co. in Philadelphia. "If you let it go into the oven white, it'll come out of the oven white."

That's because the alkaline lye bath affects the way the Maillard reaction plays out when the pretzel bakes, says Bread Science author Emily Buehler. The Maillard process is integral to all bread baking — it shapes the way the crust forms and tastes. In the case of the pretzel, the Maillard reaction is responsible for the deep brown crust, crunchy arms and distinctive taste.

At its most basic, the Maillard process is a heat-activated reaction between small sugars and amino acids. Dipping dough in lye alters the ratio between sugar and protein, because lye breaks proteins present in the dough into smaller bits. Those are the small amino acids that then combine with sugars in the dip to create the flavor compounds at the pretzel's crust.

My mom always told me that lye was what made a German pretzel different from an American pretzel, but that doesn't necessarily seem to be the case.

She doesn't even use real lye, she just puts in massive amounts of baking soda to make a stronger solution. But she still insists that she hasn't found a good Oktoberfest pretzel in the U.S.

Büchler says he tried buying lye in the states, but it doesn't live up to what he imports from Germany for his pretzels.

And those commercial soft pretzels? Forget about it. "You get the same pretzel in a Philadelphia sports stadium that you'll get in the San Francisco stadium, in a Buffalo sports stadium, New England — you'll still get the same pretzel, which is a three-ring, frozen pretzel," Tonelli laments.

My mom adds that the time the pretzel stays in the bath and the heat of the oven are also crucial. But maybe it's also partly that fresh-baked pretzels are a form of comfort food, reminding you of home, whether it's Philadelphia or Germany.

If you want to make real Bavarian pretzels, here's my mom's recipe. It has the original Metric system measurements, so grab a kitchen scale for this one.

Nina Goebel's Bavarian Pretzels

500 grams flour
1 packet rapid rise yeast
1 teaspoon salt
200-250 milliliters hot water (almost boiling)
60 grams baking soda
1 liter of water
Coarse kosher salt (for sprinkling just before baking)

Preheat oven to 400 F (200 C)

In a food processor with dough-blade attachment, mix yeast, hot water, salt and flour. Place into a bowl and cover with a moist kitchen towel. Let the dough rise for about two hours.

Form dough into pretzels, rolls or whatever shape you prefer. (Note: The actual pretzel shape is really difficult to get right; rolls are far easier)

Mix baking soda into water and bring to a boil. Dip pretzels for 30 seconds to a minute, turn and leave in the solution for another 30 seconds. Take them out carefully with a slotted spoon and dry off, patting with a paper towel. Place onto a cookie sheet lined with parchment paper. Sprinkle with salt.

Bake for about 14-20 minutes, until "nice and brown."

Important: Avoid touching the dough after dipping it into the baking soda mixture, and keep it off of aluminum surfaces. It's not lye, but it's still corrosive.

For A Proper Pretzel Crust, Count On Chemistry And Memories (2024)

FAQs

Is baking pretzels a chemical change? ›

Have students recall that baking powder, the chemical leavener used in the Whole Wheat Soda Bread, produces CO2 to make bread rise. Explain that for the Soft Pretzels we will use a biological leavener, yeast, to create the chemical reaction that will make our pretzels rise.

What chemical is used in pretzels? ›

Lye is primarily used to make pretzels, and it's the reason for their unmistakable shiny, mahogany color. To prepare, shaped pretzels are dipped in a lye bath, then baked in the oven.

What is the secret ingredient which makes a pretzel taste like a pretzel? ›

The answer lies in a brief dip in an alkaline water bath before baking. This bath essentially gelatinizes the outside of the pretzel, preventing it from fully “springing” during baking (as bread does) and giving pretzels their signature chewy crust. It also gives them their unique and indelible “pretzel” flavor.

What is the ratio of lye to water for pretzels? ›

In a deep bowl, wearing rubber or latex gloves, make a solution of ½ cup lye and 10 cups water (or 1 part lye to 20 parts water); pour lye carefully into water to avoid splashing. Dip each pretzel in solution, turning it over for 10 to 15 seconds, and place back on baking sheet. Sprinkle pretzels with salt.

What chemical change happens when you bake? ›

Sugar Reacts With Heat and Proteins to Create the Perfect Crust. You know your cake is done baking when you pull it out of the oven and see that perfect golden brown crust on top. That sweet, toasted crust is the result of a chemical reaction between sugars and proteins called the Maillard reaction.

What is the science behind the pretzel? ›

In the case of the pretzel, the Maillard reaction is responsible for the deep brown crust, crunchy arms and distinctive taste. At its most basic, the Maillard process is a heat-activated reaction between small sugars and amino acids.

What is the secret solution for Auntie Anne's pretzels? ›

While dough is rising, prepare a baking soda water bath with 2 cups warm water and 2 tbsp baking soda. Be certain to stir often. After dough has risen, pinch off bits of dough and roll into a long rope (about 1/2 inch or less thick) and shape. Dip pretzel in soda solution and place on greased baking sheet.

What is the lie for making pretzels? ›

Dipping the dough in a lye solution gives traditional German pretzels their characteristic salinity; chew; and smooth mahogany exterior, but the strong alkali (sodium hydroxide) is corrosive and can burn your skin, so it must be handled with caution.

Does Auntie Anne's use lye? ›

Well, the cheery ladies were very clear with me: they do NOT use lye. No sodium hydroxide/poison/caustic soda—none whatsoever—in their pretzels. (They do, however, dip their pretzels in a baking soda solution.) So there you have it.

Do you have to boil pretzels before baking? ›

Like bagels, pretzels are made in boiling water prior to baking to give them their snappy outsides and chewy insides (messy!). Soft pretzels must be boiled, or dipped in a baking soda bath (or lye if you're gusty and strict with your pretzel traditions). THEN, they can be baked.

Is baking soda or lye better for pretzels? ›

Lye has a pH of around 13 whereas baking soda has a pH of around 8. This extra alkalinity accelerates the Maillard reaction, allowing that caramelization to develop on the exterior of the pretzels. That ultra-deep color and slightly crispy, crunchy exterior crust is only made possible with lye.

Is baking bread physical or chemical change? ›

It is a chemical change. The transformation of flour into gluten chains creates a new substance with different properties, and an altered chemical composition.

What changes happened to the pretzel during baking? ›

Here is the important part: the Maillard reaction, is accelerated in an alkaline environment. The lye, as well as the baking soda, increases the alkalinity of the surface of the pretzel and allows for a browning reaction between amino group and reducing sugars to occur.

Is baking cookies physical or chemical change? ›

Baking cookies is a chemical change. This is because new substances are formed during the process, such as carbon dioxide gas from the reaction of baking soda or powder with other ingredients. The process is irreversible under normal conditions, which is a key characteristic of chemical changes.

Is baking pancakes a chemical change? ›

Cooking pancake batter and burning paper or wood are examples of chemical changes. Generally, a chemical change is irreversible and will create a new material that looks, feels, smells, and/or tastes very different. The kitchen is a great place for students to make observations and explore the basics of chemistry.

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